Low Energy Research Articles

Effect of non-metal doping on the optoelectronic properties of ZrS2/ZrSe2 heterostructure under strain: a first-principles study.

In this paper, we systematically studied the effects of non-metallic element (B, C, N, O, F) doping and biaxial stretching on the photoelectric properties of ZrS2/ZrSe2 heterostructures by using the first-principles calculation method based on density functional theory. The results show that the p-type doping is realized by B, C, and N atom doping, and the n-type doping is realized by O and F atom doping. The doping of B and C atoms produces impurity energy levels in the band gap, which affects the conductivity of the heterostructure. The band gap of N and O atom-doped heterostructures increases under tensile strain, but it is still a direct band gap. The analysis of the optical properties of the heterostructures shows that the doping of non-metallic atoms can adjust the optical absorption rate and reflectivity of the heterostructures. Under the action of tensile strain, the optical properties of the doped heterostructures have changed significantly in the low-energy region. This article provides a theoretical basis for the future application of ZrS2/ZrSe2 heterostructures. This paper uses the first-principles calculation method based on density functional theory. The PBE exchange-correlation functional based on generalized gradient approximation (GGA) is selected for the specific calculation, and the crystal structure is geometrically optimized by the ultrasoft pseudopotential method. It is verified that when the cutoff energy of the ZrS2/ZrSe2 heterostructure is 500 eV, the K-point grid is selected to be 10 × 10 × 2 with the lowest energy, so the cutoff energy is selected to be 500 eV. The K-point grid is selected to be 10 × 10 × 2. The convergence limits for structural optimization are as follows: the maximum force between atoms is 0.01 eV/Å, the convergence threshold of the maximum energy change is set to 10-9 eV/atom, and the convergence threshold of the maximum displacement is 0.001 Å. In order to avoid the influence of atomic periodic motion between different atomic layers, a vacuum layer of 20 Å is added in the vertical direction. Considering the interaction of vdW between the interfaces, the DFT-D2 method is used to verify. The optical properties were calculated by the random phase approximation method, and the K-point grid was selected as 12 × 12 × 2.

Cyanogel-Induced Facile Synthesis of Palladium Hydride for Electrocatalytic Oxygen Reduction.

Palladium hydride (PdHx) is one of the well-known electrocatalytic materials, yet its synthesis is still a challenge through an energy-efficient and straightforward method. Herein, we propose a new and facile cyanogel-assisted synthesis strategy for the preparation of PdH0.649 at a mild environment with NaBH4 as the hydrogen source. Unlike traditional inorganic Pd precursors, the unique Pd-CN-Pd bridge in Pdx[Pd(CN)4]y·aH2O cyanogel offers more favourable spatial sites for insertion of H atoms. The characteristic three-dimensional backbone of cyanogel also acts as a support scaffold resulting in the interconnected network structure of PdH0.649. Due to the incorporation of H atoms and interconnected network structure, the PdH0.649 achieves a high half-wave potential of 0.932 V, a high onset potential of 1.062 V, and a low activation energy, as well as a long-term lifetime for oxygen reduction reaction. Theoretical calculation demonstrates a downshift of the d-band centre of Pd in PdH0.649 owing to the dominant Pd-H incorporation that weakens the binding energies of the *OH intermediate species. Zn-air batteries (ZAB) based on PdH0.649 exhibits high power density, competitive open circuit voltage, and good stability, exceeding that of commercial Pt black.

Replacing a Cysteine Ligand by Selenocysteine in a [NiFe]-Hydrogenase Unlocks Hydrogen Production Activity and Addresses the Role of Concerted Proton-Coupled Electron Transfer in Electrocatalytic Reversibility.

Hydrogenases catalyze hydrogen/proton interconversion that is normally electrochemically reversible (having minimal overpotential requirement), a special property otherwise almost exclusive to platinum metals. The mechanism of [NiFe]-hydrogenases includes a long-range proton-coupled electron-transfer process involving a specific Ni-coordinated cysteine and the carboxylate of a nearby glutamate. A variant in which this cysteine has been exchanged for selenocysteine displays two distinct changes in electrocatalytic properties, as determined by protein film voltammetry. First, proton reduction, even in the presence of H2 (a strong product inhibitor), is greatly enhanced relative to H2 oxidation: this result parallels a characteristic of natural [NiFeSe]-hydrogenases which are superior H2 production catalysts. Second, an inflection (an S-shaped "twist" in the trace) appears around the formal potential, the small overpotentials introduced in each direction (oxidation and reduction) signaling a departure from electrocatalytic reversibility. Concerted proton-electron transfer offers a lower energy pathway compared to stepwise transfers. Given the much lower proton affinity of Se compared to that of S, the inflection provides compelling evidence that concerted proton-electron transfer is important in determining why [NiFe]-hydrogenases are reversible electrocatalysts.

Multifunctional in vitro, in silico and DFT analyses on antimicrobial BagremycinA biosynthesized by Micromonospora chokoriensis CR3 from Hieracium canadense

Among the actinomycetes in the rare genera, Micromonospora is of great interest since it has been shown to produce novel therapeutic compounds. Particular emphasis is now on its isolation from plants since its population from soil has been extensively explored. The strain CR3 was isolated as an endophyte from the roots of Hieracium canadense, and it was identified as Micromonospora chokoriensis through 16S gene sequencing and phylogenetic analysis. The in-vitro analysis of its extract revealed it to be active against the clinical isolates of methicillin-resistant Staphylococcus aureus (MRSA) and Candida tropicalis (15 mm). No bioactivity was observed against Gram-negative bacteria, Escherichia coli ATCC 25922, and Klebsiella pneumoniae ATCC 706003. The Micromonospora chokoriensis CR3 extract was also analyzed through the HPLC-DAD-UV–VIS resident database, and it gave a maximum match factor of 997.334 with the specialized metabolite BagremycinA (BagA). The in-silico analysis indicated that BagA strongly interacted with the active site residues of the sterol 14-α demethylase and thymidylate kinase enzymes, with the lowest binding energies of − 9.7 and − 8.3 kcal/mol, respectively. Furthermore, the normal mode analysis indicated that the interaction between these proteins and BagA was stable. The DFT quantum chemical properties depicted BagA to be reasonably reactive with a HOMO-LUMO gap of (ΔE) of 4.390 eV. BagA also passed the drug-likeness test with a synthetic accessibility score of 2.06, whereas Protox-II classified it as a class V toxicity compound with high LD50 of 2644 mg/kg. The current study reports an endophytic actinomycete, M. chokoriensis, associated with H. canadense producing the bioactive metabolite BagA with promising antimicrobial activity, which can be further modified and developed into a safe antimicrobial drug.

Efficient Capture and Electroreduction of Dilute CO2 into Highly Pure and Concentrated Formic Acid Aqueous Solution.

High-purity CO2 rather than dilute CO2 (15 vol %, CO2/N2/O2 = 15:80:5, v/v/v) similar to the flue gas is currently used as the feedstock for the electroreduction of CO2, and the liquid products are usually mixed up with the cathode electrolyte, resulting in high product separation costs. In this work, we showed that a microporous conductive Bi-based metal-organic framework (Bi-HHTP, HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) can not only efficiently capture CO2 from the dilute CO2 under high humidity but also catalyze the electroreduction of the adsorbed CO2 into formic acid with a high current density of 80 mA cm-2 and a Faradaic efficiency of 90% at a very low cell voltage of 2.6 V. Importantly, the performance in a dilute CO2 atmosphere was close to that under a high-purity CO2 atmosphere. This is the first catalyst that can maintain exceptional eCO2RR performance in the presence of both O2 and N2. Moreover, by using dilute CO2 as the feedstock, a 1 cm-2 working electrode coating with Bi-HHTP can continuously produce a 200 mM formic acid aqueous solution with a relative purity of 100% for at least 30 h in a membrane electrode assembly (MEA) electrolyzer. The product does not contain electrolytes, and such a highly concentrated and pure formic acid aqueous solution can be directly used as an electrolyte for formic acid fuel cells. Comprehensive studies revealed that such a high performance might be ascribed to the CO2 capture ability of the micropores on Bi-HHTP and the lower Gibbs free energy of formation of the key intermediate *OCHO on the open Bi sites.

Mechanical characteristics of auxetic composite honeycomb sandwich structure under bending

Auxetic honeycomb sandwich structures (AHS) composed of a single material generally exhibit comparatively lower energy absorption (EA) and platform stress, as compared to traditional non-auxetic sandwich structures (TNS). To address this limitation, the present study examines the use of aluminum foam (AF) as a filling material in the re-entrant honeycomb sandwich structure (RS). Filling the AHS with AF greatly enhances both the EA and platform stress in comparison to filling the TNS with AF, while the auxetic composite honeycomb sandwich structure effectively addresses interface delamination observed in traditional non-auxetic composite sandwich structures. Subsequently, the positive–negative Poisson’s ratio coupling designs are proposed to strengthen the mechanical features of a single honeycomb sandwich structure. The analysis results show that the coupling structure optimizes the mechanical properties by leveraging the high bearing capacity of the hexagonal honeycomb and the great interaction between the re-entrant honeycomb and the filling material. In contrast with traditional non-auxetic sandwich structures, the proposed auxetic composite honeycomb sandwich structures demonstrate superior EA and platform stress performance, suggesting their immense potential for utilization in protective engineering.

Study of 113In(α, α) elastic scattering to determine α-optical potential relevant for astrophysical γ-process

Abstract The α-optical potential is one of the key input parameters used to measure the reaction rate of the (γ, α)-process using the Hauser-Feshbach statistical model and the principle of detailed balance. α-elastic scattering experiment on 113In p-nucleus was carried out in the energy range E lab = 26−32 MeV. The vacuum evaporation technique was used to prepare the 113In target (∼86 μg cm−2). An energy-dependent local optical potential parameters set was obtained by analysing the experimental elastic scattering angular distribution data. The local potential parameters are extrapolated for lower energies and are used to calculate the 113In(α, γ) reaction cross-section.

Pyridinium Ylide-Mediated Diastereoselective Synthesis of Spirocyclopropanyl-pyrazolones via Cascade Michael/Substitution Reaction.

We have devised a highly diastereoselective formal [2 + 1] annulation reaction of arylidene/alkylidine-pyrazolones with in situ-generated supported as well as standard pyridinium ylides to construct spirocyclopropanyl-pyrazolones. The cascade approach exhibits a wide range of functional group tolerance, gram-scale capability, and substrate versatility. A diverse range of spirocyclic cyclopropanes was synthesized extensively with both mediators, and the supported pyridine was reused in subsequent cycles. Density functional theory calculations confirmed the formation of spirocyclopropane as the lower energy pathway.

Thermodynamic signatures and phase transitions in high-energy Au–Au collision

In this study, we systematically investigate the dynamics of various hadrons namely π +, π −, K +, K −, p, p¯ , Λ, Λ¯ , Ξ− and Ξ¯+ produced in central Au–Au collisions. We analyze data of AGS and RHIC, which span a broad range of collision energies, ranging from sNN = 1.9 to 200 GeV. To analyze the transverse momentum (p T ) and transverse mass (m T ) distributions, we employ a two-component standard distribution function, achieving a very good representation of the experimental data across these energy regimes. We extract key thermodynamic parameters, including the effective temperature T, the mean transverse momentum 〈p T 〉, and the initial temperature T i , and analyze their dependence on the values of collision energy and particle mass. Our findings reveal a distinct transition behaviour around sNN=19.6GeV . Below sNN=19.6GeV , the values of T, 〈p T 〉, and T i increase monotonically for all hadrons due to higher energy transfer into the system. Above this energy threshold, these extracted parameters plateau, suggesting that the additional energy is utilized as latent heat for phase transition rather than increasing the system’s temperature. These observations delineate two distinct regions: a hadron-dominated region at lower energies and a parton-dominated region at higher energies, each potentially indicative of different phases of matter, with the latter possibly signalling the onset of a quark–gluon plasma. The study thus provides critical insights into the complex interplay of thermodynamics, phase transitions, and particle interactions in high-energy Au–Au collisions.

Nonlinear excitation of energetic particle driven geodesic acoustic mode by Alfvén instability in ASDEX-Upgrade tokamak

Abstract Recently, the coexistence of multiple energetic particle driven instabilities was observed in experiments on the ASDEX-Upgrade tokamak[P. Lauber et al., EX 1-1, 27th IAEA Fusion Energy Conference, 22-27 October 2018, Gandhinagar, India]. A hybrid simulation using the MEGA code was performed to investigate the properties of those instabilities. The basic mode properties obtained in the simulations, such as mode frequencies, mode numbers, and inward energetic particle (EP) redistribution, are in good agreement with the experiments. It is found that the energetic particle driven geodesic acoustic mode (EGAM) is initially stable, then zonal flow gradually occurs with the growth of the Alfvén instability, and finally, the EGAM is nonlinearly excited and the amplitude exceeds the Alfvén instability. The dependence of EGAM properties on EP pressure and pitch angle distribution is analyzed. The EGAM amplitude increases with EP pressure. The nonlinearly excited EGAM is a high-frequency branch that appears even under the condition of a slowing-down EP distribution. The resonant particles are also analyzed, but the dominant resonant particles of the EGAM in the linear growth phase are not found because the EGAM does not grow in the linear regime. In the phase space of pitch angle variable Λ and energy E, it is found that initially the Alfvén instability is excited by EPs with poloidal frequency 70 kHz, then, after the saturation of the Alfvén instability, the resonance region moves towards lower energy and touches the EGAM resonance line, and finally, EGAM is excited by the particles with poloidal frequency 50 kHz. This process is a kind of resonance overlap.

A crinoid fauna and a new species of Pycnocrinus from the Martinsburg Formation (Upper Ordovician), lower Hudson Valley, New York

Abstract A new crinoid fauna has been discovered in the Upper Ordovician (Katian) Martinsburg Formation at a small shale quarry, locally known as the ‘Shale Bank,’ on the Shawangunk Ridge in Ulster County, NY. The assemblage, which is from a relatively low energy, offshore mud-bottom environment, includes four identified species, including a new species of glyptocrinid camerate, Pycnocrinus mohonkensis n. sp., described herein. Crinoid taxa in order of increasing branch density in the assemblage include (1) the dicyclic inadunate Merocrinus curtus with irregularly isotomous and heterotomous, non-pinnulate arms and a stout cylindrical column exceeding 700 mm; (2) the disparids Cincinnaticrinus varibrachialus, with heterotomous non pinnulate arms, and Ectenocrinus simplex, with extensively branched ramulate arms and meric columns of 460–500 mm; and (3) the camerate Pycnocrinus mohonkensis n. sp., with uniserial pinnulate arms and a somewhat shorter column. Some cylindrical stems with nodose and holomeric columnals are thought to belong to unknown camerate crinoids with pinnulate arms. Filtration theory is used to model food capture in the Martinsburg crinoids. Surprisingly, even densely pinnulate camerates were able to survive in this setting, suggesting that ambient currents attained velocities exceeding 25 cm/sec even in this offshore setting. Similar assemblages were widespread in eastern Laurentia during the Late Ordovician. UUID: http://zoobank.org/23ca31e8-f572-4520-ba1d-891e3abb950d

Evaluation of hydrogen/ammonia substitute fuel mixtures for methane: Effect of differential diffusion

One strategy for utilizing ammonia as an energy vector is to replace conventional hydrocarbons with hydrogen-enriched ammonia in existing or retrofitted combustors. However, the strong differential diffusion effect of hydrogen can significantly alter the combustion properties and cause challenges in combustor operability. Therefore, this numerical study performs a systematic investigation on the effect of differential diffusion on fundamental combustion properties of ammonia/hydrogen fuel blends. The investigated combustion properties span from the initiation of combustion, i.e., ignition, to stretched flame propagation and ultimately to flame stabilization mechanisms. The objective is to evaluate the feasibility of hydrogen/ammonia/air mixtures as substitutes for methane/air particularly considering the implications of differential diffusion effects. To this end, four fuel blends with similar unstretched burning properties are selected: fuel lean ammonia/hydrogen (AH-L), fuel rich ammonia/hydrogen (AH-R), fuel lean methane (M-L) and fuel lean methane/hydrogen (MH-L). First, the forced ignition and stretched flame propagation are evaluated. It is found that the AH-L (AH-R) mixture has a large negative (positive) Markstein length, and thereby among the selected fuel blends, AH-L (AH-R) has the lowest (highest) minimum ignition energy. Then flame stabilization mechanisms are investigated. For a stable flame, AH-L (AH-R) has an intensified (weakened) flame base and a weak (strong) flame tip, which shows a higher flashback (blow-off) propensity. Based on the critical gradient theory, a novel stability regime diagram is proposed. With the regime diagram, the flame stabilization limits (central flashback, boundary layer flashback, stable, and blow-off) and flow conditions can be determined for burners of different sizes.

Isolation, Virtual Screening, and Evaluation of Hazelnut-Derived Immunoactive Peptides for the Inhibition of SARS-CoV-2 Main Protease.

The aim of this study is to validate the activity of hazelnut (Corylus avellana L.)-derived immunoactive peptides inhibiting the main protease (Mpro) of SARS-CoV-2 and further unveil their interaction mechanism using in vitro assays, molecular dynamics (MD) simulations, and binding free energy calculations. In general, the enzymatic hydrolysis components, especially molecular weight < 3 kDa, possess good immune activity as measured by the proliferation ability of mouse splenic lymphocytes and phagocytic activity of mouse peritoneal macrophages. Over 866 unique peptide sequences were isolated, purified, and then identified by nanohigh-performance liquid chromatography/tandem mass spectrometry (NANO-HPLC-MS/MS) from hazelnut protein hydrolysates, but Trp-Trp-Asn-Leu-Asn (WWNLN) and Trp-Ala-Val-Leu-Lys (WAVLK) in particular are found to increase the cell viability and phagocytic capacity of RAW264.7 macrophages as well as promote the secretion of the cytokines nitric oxide (NO), tumor necrosis factor-α (TNF-α), and interleukin-1β (IL-1β). Fluorescence resonance energy transfer assay elucidated that WWNLN and WAVLK exhibit excellent inhibitory potency against Mpro, with IC50 values of 6.695 and 16.750 μM, respectively. Classical all-atom MD simulations show that hydrogen bonds play a pivotal role in stabilizing the complex conformation and protein-peptide interaction. Molecular Mechanics/Generalized Born Surface Area (MM/GBSA) calculation indicates that WWNLN has a lower binding free energy with Mpro than WAVLK. Furthermore, adsorption, distribution, metabolism, excretion, and toxicity (ADMET) predictions illustrate favorable drug-likeness and pharmacokinetic properties of WWNLN compared to WAVLK. This study provides a new understanding of the immunomodulatory activity of hazelnut hydrolysates and sheds light on peptide inhibitors targeting Mpro.

Critical Sensing Modalities for Hydrogen: Technical Needs and Status of the Field to Support a Changing Energy Landscape.

Decarbonization of the energy system is a key aspect of the energy transition. Energy storage in the form of chemical bonds has long been viewed as an optimal scheme for energy conversion. With advances in systems engineering, hydrogen has the potential to become a low cost, low emission, energy carrier. However, hydrogen is difficult to contain, it exhibits a low flammability limit (>40000 ppm or 4%), low ignition energy (0.02 mJ), and it is a short-lived climate forcer. Beyond commercially available sensors to ensure safety through spot checks in enclosed environments, new sensors are necessary to support the development of low emission infrastructure for production, transmission, storage, and end use. Efficient scalable broad area hydrogen monitoring motivates lowering the detection limit below that (10 ppm) of best in class commercial technologies. In this perspective, we evaluate recent advances in hydrogen gas sensing to highlight technologies that may find broad utility in the hydrogen sector. It is clear in the near term that a sensor technology suite is required to meet the variable constraints (e.g., power, size/weight, connectivity, cost) that characterize the breadth of the application space, ranging from industrial complexes to remote pipelines. This perspective is not intended to be another standard hydrogen sensor review, but rather provide a critical evaluation of technologies with detection limits preferably below 1 ppm and low power requirements. Given projections for rapid market growth, promising techniques will also be amenable to rapid development in technical readiness for commercial deployment. As such, methods that do not meet these requirements will not be considered in depth.

Optimization of Electrochemical Reduction of Biomass Derived 5-Hydroxymethylfurfural (HMF): A Volcano Plot and Bimetallic Catalysts.

2,5-bis(hydroxymethyl)furan (BHMF) derived from 5-Hydroxymethylfurfural (HMF) through a hydrogenation process has extensive applications in the production of resins, polymers, and artificial fibers. However, screening out the candidate and then modulating the active site to optimize the catalyst for high yield of BHMF are currently insufficient. In this study, Gibbs free energy diagrams of the reduction of HMF on 13 metals were presented, along with the identification of the rate-determining step (RDS) with the highest reaction barrier for each metal. We attempted to construct a volcano plot for HMFRR reaction. Additionally, a strategy was proposed to adjust the reaction barriers of RDS by combining two appropriate metals. Further experiments confirmed that Pb with the lowest energy barrier exhibited the highest HMF conversion (BHMF selectivity) among single metals. The modified catalyst by doping Ag on Pb, further boosted the HMF conversion (BHMF selectivity) from 42.1% (59.4%) to 80.8% (80.9%), respectively. These results provide an approach to rationally design and construct the catalyst system for efficient conversion of HMF.

Research on Energy Loss of Optimization of Inducer–Impeller Axial Fit Dimensions Based on Wave-Piercing Theory

With the development of modern fluid machinery, the energy density of pumps is gradually being improved, and at the same time, higher demands are being placed on the cavitation performance, hence the introduction of the inducer and centrifugal impeller to form a dynamic–dynamic series structure. However, there are strict constraints on the axial size of pumps in fields such as firefighting and aerospace. The traditional empirical formula no longer satisfies the need to fit the axial dimensions between the induced wheel and the impeller at high velocities. Therefore, based on the wave-piercing theory, the drag reduction coefficient is introduced to explore the optimal axial fit size from the perspective of energy characteristics. This paper focuses on the influence of the inducer’s wake on the energy characteristics of downstream impellers, and conducts the following research: by adjusting the axial matching dimensions between the upstream inducer and the centrifugal impeller in the initial model, ten sets of axial distance models with matching dimensions of KD are designed, and the drag reduction coefficient is embedded to determine the optimal axial distance. The results show that the optimal axial distance is 0.2D, which is far lower than the axial distance value of 0.42D obtained from the traditional empirical formula for axial matching dimensions. Meanwhile, this paper uses tangential velocity, the inlet flow angle of the impeller, entropy production theory, and other indicators to analyze the internal energy loss of the high-speed vehicular fire pumps one by one. All of them confirm that the impeller in the high-speed vehicular fire pump has the lowest energy loss and optimal performance at an axial distance of 0.2D. Specifically, at this axial distance, the head can reach 259 m, and the hydraulic efficiency is as high as 83.62%. Thus, the feasibility of determining the axial placement of the impeller using the drag coefficient is validated. This research provides new insights into determining the axial coordination dimensions between the inducer and the impeller.

Development of Diffraction Research Methodologies for Mediloy S-CO Alloy Speciments Made Using LPBF Additive Manufacturing

Abstract This study focuses on the application and improvement of diffraction measurement methodologies for the optimization of manufacturing parameters of CoCr alloy components made by additive manufacturing (AM) – particularly for Mediloy S-Co alloy specimens made using Laser Powder Bed Fusion (LPBF) additive manufacturing. We measured the phase composition of specimens obtained in AM processes, the measurement of residual stresses resulting from the manufacture of these printed parts, as well as the effectiveness of stress relaxation through the use of heat treatments dedicated to this type of material. Findings reveal several insights into how printing strategies affect the porosity and residual stresses in additive manufacturing. Specimens with higher porosity, particularly those created using specific strategies that resulted in lower energy densities, exhibited lower residual stresses. Notably, printing direction and energy density were found to significantly affect the mechanical stresses within the specimens, with directional choices playing a critical role in the final properties of the parts. Additionally, our findings underscore the complex relationship between various printing parameters and the development of mechanical stresses, highlighting the impact of adjustments in printing strategy on the properties of printed components.

Mixing of a cylindrical gravity current in a stratified ambient

Simulation results from direct numerical simulations (DNSs) of cylindrical gravity currents propagating into a linearly stratified ambient with stratification strengths ranging from 0 to 0.8, at a moderate Reynolds number of Re=3450 are presented. The simulations are based on the incompressible Navier–Stokes equations, assuming small density differences such that the Boussinesq approximation is valid. The density of the ambient fluid increases linearly from the top (ρ0) to the bottom (ρb) of the domain. A comparative analysis is conducted between the stratified cases and the unstratified case to investigate the impact of ambient stratification strength on the mixing behaviour of cylindrical gravity currents. The energy conversion processes are analysed using the mechanical framework proposed by Winters et al. (1995). The energy budget is formulated by considering gravitational available potential energy, and the evolution of potential energy due to reversible stirring and irreversible diapycnal mixing in the system. The findings reveal a decrease in available potential energy and kinetic energy with increasing stratification strength, indicating lower energy exchange for gravity currents propagating in the stratified environment. Instantaneous and cumulative mixing efficiency calculations during the slumping phase indicate that Kelvin–Helmholtz billow play an important role in stirring the heavy fluid and causing irreversible mixing with the ambient fluid.

Hydrodynamic Performance Study of a Reciprocating Plate Column Dirven by Electro-permanent Magnet Technology

The reciprocating plate column is a kind of column with the plates driven by a geared motor, and it has advantages in regard to efficiency compared to traditional columns in the extraction process, however, it comes with an increase in energy consumption. A new type of reciprocating plate column driven by electro-permanent magnet technology (EPM) is proposed in this paper to obtain a better performance with lower energy consumption. The feasibility and performance of the proposed column is studied by numerical simulation and experiments with a kerosene–water system. The electro-permanent magnet chuck could provide a maximum amplitude of 12 mm in this study. Kerosene was used as the dispersed phase, and deionized water was used as the continuous phase, in a laboratory-scale 35 mm diameter reciprocating plate column driven by EPM. Hydrodynamic performance experiments were carried out with different flowrates of both phases and reciprocating frequencies. The experimental results show that the electro-permanent magnet chuck, which serves as the driving device of the reciprocating plate column, plays the role of adding energy and increasing the droplet breakage. In addition, the energy consumption of the reciprocating plate column with traditional geared motor and electro-permanent magnet chuck is calculated respectively. Compared with the traditional geared motor, the energy saving of the electro-permanent magnet chuck is as high as 98.55%.

Towards the Optimization of a Photovoltaic/Membrane Distillation System for the Production of Pure Water

The production of pure water plays a pivotal role in enabling sustainable green hydrogen production through electrolysis. The current industrial approach for generating pure water relies on energy-intensive techniques such as reverse osmosis. This study unveils a straightforward method to produce pure water, employing real-world units derived from previously simulated and developed laboratory devices. This demonstrated system is cost-effective and boasts low energy consumption, utilizing membrane distillation (MD) driven by the waste heat harnessed from photovoltaic (PV) panels. In a previous study, modeling simulations were conducted to optimize the multi-layered MD system, serving as a blueprint for the construction of prototype devices with a suitable selection of materials, enabling the construction of field-testable units. The most efficient PV-MD device, featuring evaporation and condensation zones constructed from steel sheets and polytetrafluoroethylene (PTFE) membranes, is capable of yielding high-purity water with conductivity levels below 145 μS with high flux rates.